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Glow Inc.

Solvent Paints (All Colors) MSDS

GHS Revision Date:   3/28/2019                                                                                                                                                                 

  1. IDENTIFICATION

Product Name:

Product Number :

Product Class:

Chemical Formula:

 

General Use :

 

Restrictions :

 

Manufacturer Information:

 

 

 

 

 

Emergency Contact Number:

Glow Inc. Solvent Based Glow in the Dark Paint 

ALL COLORS

Trade Product

Mixture          

 

art & craft paint

 

N/A

 

Glow Inc.

1539 Florida Ave

Severn, MD 21144

Phone: 704-456-9462

EMAIL:

 

CHEMTREC. 1-800-424-9300  

 
  1. HAZARD IDENTIFICATION

GHS Classification

Flam. Liquid . 2 H225, Acute Toxic. 4 (Oral) H302, Skin Irritant. 2 H315,Eye Irritant . 2A H319, May Cause dizziness and drossiness STOT SE 3 H336

 

SINGLE WORD IDENTIFIER : DANGER

 

PHYSICAL STATE: Liquid

 

Labelling Requirements GHS                                        

    

Hazard Statement

H225 - Highly flammable liquid and vapor, H302 - Harmful if swallowed, H315 - Causes skin irritation, H319 - Causes serious eye irritation, H336 - May cause drowsiness or dizziness

 

Precautionary Statement:

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking, P233 - Keep container tightly closed

P243 - Take precautionary measures against static discharge, P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

P264 - Wash thoroughly after handling, P270 - Do not eat, drink or smoke when using this product

P301+P312 - IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell

P302+P352 - IF ON SKIN: Wash with plenty of water

P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing

P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses continue rinsing

P330 - If swallowed, rinse mouth

P332+P313 - If skin irritation occurs: Get medical advice/attention, P337+P313 - If eye irritation persists: Get medical advice/attention, P370+P378 - In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam, or water

fog for extinction, P403+P233/235 - Store in a well-ventilated place. Keep container cool and tightly closed

P405 - Store locked up,

P501 - Dispose of contents/container in accordance with local and national regulations.

 

HAZARD IDENTIFICATION CONTINUED

 

Other Hazards

For handling bulk quantities (>5 liters):

P240 - Ground/bond container and receiving equipment

P241 - Use explosion-proof electrical/ventilating/lighting equipment

P242 - Use only non-sparking tools

 
  1. 1.      COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name

CAS#

Weight %

Hazard Class

OSHA/ACGIH PEL

ACGIH TLV*

ETHYL ACETATE

141-78-6

28-40

Flam/ Eye Irrit

400ppm

200ppm

ISOPROPYL ALCOHOL

67-63-0

1-8

Flam

400ppm

500ppm

N-BUTYL ACETATE

123-86-4

15-33

Flam/Acute Toxic /Eye Damage

150ppm

200ppm

NITROCELLULOSE

9004-70-0

5-12

Flam/ Skin & Eye Iritt

N/A

N/A
  1. 2.       FIRST AID MEASURES

 

First-aid measures after inhalation: If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell.

 

First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash contaminated clothing before reuse. Destroy contaminated shoes.

 

First-aid measures after eye contact: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

 

First-aid measures after ingestion: If swallowed, rinse mouth with water (only if the person is conscious). Do NOT induce vomiting unless directed to do so by medical personnel. Call a POISON CENTER/doctor/physician if you feel unwell.

Symptoms and Effects, Acute and Chronic

Symptoms/injuries after inhalation: Inhalation may cause: irritation, cough, shortness of breath. May cause drowsiness or dizziness.

Symptoms/injuries after skin contact: Causes skin irritation. Prolonged or repeated contact may cause skin to become dry or cracked.

Symptoms/injuries after eye contact: Causes serious eye irritation.

 

Note to Medical Professional all treatments should be based on observed signs and symptoms of distress in the patient.

 
  1. 3.      FIRE-FIGHTING MEASURES :

Suitable extinguishing media: Preferably: alcohol resistant foam. Water spray. Polyvalent foam. BC powder. Carbon dioxide.

 

Hazardous Products of Combustion: May form: carbon dioxide and carbon monoxide.

 

Fire and Explosion Hazards: Material is highly volatile and readily gives off vapors which may travel along the ground or be moved by ventilation and ignited by pilot lights, other flames, sparks, heaters, smoking, electric motors, static discharge, or other ignition sources at locations distant from material handling point- Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.

 

Fire Fighting Instructions:  Wear a self-contained breathing apparatus with a full face piece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment. Exercise caution when fighting any chemical fire. All extinguishing media can be used.

 

  1. 1.      ACCIDENTAL RELEASE MEASURES

 

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

 

Personal Precautions:  Wear appropriate protective equipment including respiratory protection as conditions warrant.

Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

 

Small Spill: Absorb liquid on vermiculite, floor absorbent or other absorbent material.Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal.

 

Large Spill: Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source- Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred.

Avoid all eyes and skin contact and do not breathe vapor and mist. Wear suitable gloves resistant to chemical penetration: butyl rubber.

 

Emergency procedures: Avoid all unnecessary exposure. Stop leak without risks if possible. Ventilate area.

 

      

  1. 2.      HANDLING AND STORAGE  

 

Handling: Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Avoid all eyes and skin contact and do not breathe vapor and mist. Handle in a well-ventilated area. Prohibit all sources of sparks and ignition. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

 

Storage conditions: Keep only in the original container in a cool, well ventilated place away from: Heat sources, Direct sunlight, and incompatible materials. Keep container closed when not in use. Store in a cool area. Keep out of direct sunlight. Store in a dry area. Store in a dark area. Ventilation at floor level. Fireproof storeroom. Provide for an automatic sprinkler system. Provide for a tub to collect spills..

 

Incompatible products: Strong bases. Strong acids.

 

Incompatible materials:  Sources of ignition. Direct sunlight.

 

Storage temperature: 15 - 20 °C

 

Heat and ignition sources: KEEP SUBSTANCE AWAY FROM: heat sources. Ignition sources.

 

Prohibitions on mixed storage: KEEP SUBSTANCE AWAY FROM: oxidizing agents. Reducing agents. (Strong) acids. (Strong) bases. Halogens. Amines.

 

Precaution to be taken in handling and storing Store large quantities only in buildings designed to comply with osha 1910.106.  Store in cool area.

 

Hygiene measures: Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

 

 


  1. 1.      EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Appropriate engineering controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.

 

Eye Protection: Chemical splash gaggles In compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative.

 

Skin Protection: Near resistant gloves (consult your safety equipment supplier)., To prevent repeated or prolonged skin contact, wear impervious clothing And boots..

 

Respiratory Protections: If workplace exposure limit(&) of product or any component Is exceeded (see exposure guidelines), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure,

 

Ventilation: All application areas should be ventilated in accordance with osha regulation 29cfr.1910 to keep air contaminant concentration levels below application osha permissible exposure limit or acgih's tlv  Limit.

 

Other information: Do not eat, drink or smoke during use.

 

Personal Protective Equipment Pictograms

 

   

 

Environmental Exposure Controls:

Follow best practice for site management and disposal of waste. Avoid release to the environment.

 
  1. 2.      PHYSICAL AND CHEMICAL PROPERTIES

Material Description

PhysicalForm

Liquid  

Molecular weight

Not Established

Color

Colored solution   

Flash Point

45°F

Odor

Esters  

Bulk density

Not Established

Boiling Point

171°F

Freezing Point

No Data

Decomposition  Temp

N/A

Vapor Pressure @50°C

35 – 42mm   hg

PH Rating

Not Established

Self Ignition temp

No Data

Vapor Density

3.2 to 3.6 @ 20 °C (air=1)

Ignition Distance

No Data

Water Solubility

10%

Coating VOC  

6.15 LBS

Evaporation rate

Slower than Esters

Flammability  in Air

Lower 1.0 Upper 9.0

Viscosity    

Not Established  

Melting Point  

No Data

  1. 3.      STABILITY AND REACTIVITY

 

Stability:  Stable

 

Conditions to avoid: heat sparks, open flame, static

 

Incompatibility (materials to avoid): alkaline metals, strong acids oxidizing agents

 

Hazardous decomposition or byproducts:  oxides of nitrogen-carbon dioxide/monoxide

 

Hazardous polymerization: will not occur


  1. 1.      TOXICOLOGICAL INFORMATION

Likely Routes of Exposure:The most likely routes of exposure are dermal (skin) contact and inhalation.

 

Acute exposure

 

Oral toxicity- the ld50 in rate is between 20000 mg/kg and 5000mg/kg.  Based on date or similar materials. Swallowing this material causes irritate of mouth, esophagus and stomach, with nausea, vomiting, diarrhea and abdominal pain.  Material can be aspirated into the lungs during the act of swallowing or vomiting. This could result in pulmonary edema and chemical pneumonitis.

 

Eye irritation- moderate to strong eye irritation.  Based on data from components or similar material.

 

Skin irritation- may cause skin irritation, based on data from components or similar materials.

 

Dermal toxicity- based on data from components

 

Inhalation toxicity- high concentration may cause headache, dizziness, nausea, stupor and other central nervous system effects leading to visual impairment, difficulty breathing and convulsions.

 

Respiratory irritation- nose, throat and lung irritant.  Based on data from components or similar material.

 

 


  1. 2.      ECOLOGICAL INFORMATION

Freshwater fish toxicity- not determined

Freshwater invertebrates toxicity- not determined

Algal inhibition-not determined

Saltwater fish toxicity- not determined

Bacteria toxicity- not determined

 

  1. 3.      DISPOSAL CONSIDERATIONS

 

Use only licensed transporters and permitted disposal facilities and conform to all laws.

Recycle to process, if possible. Care must be taken to prevent environmental contamination from the use of this material. The user of this material has the responsibility to dispose of unused materials, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Avoid release to the environment.

 

Waste treatment methods: Dispose in a safe manner in accordance with local/national regulations. Significant quantities of waste product residues should be processed in a suitable effluent treatment plant. Dispose of

surplus and non-recyclable products via a licensed waste disposal contractor

 
  1. 4.      TRANSPORTATION INFORMATION

Shipping information:

DOT

Shipping name: Paint    

Hazard Class: 3

UN/NA Class: UN1263

Label: flammable   

Packing Group II

  

Shipping information:

IATA

Shipping name: Paint   

Hazard Class: 3

UN/NA Class: UN1263

Label: flammable  

Packing Group II

 

 

Shipping information:

IDMG

Shipping name: Paint   

Hazard Class: 3

UN/NA Class: UN1263

Label: flammable  

Packing Group II

 

 

 
  1. 1.      REGULATORY INFORMATION

 

Listed on the United States TSCA (Toxic Substances Control Act) inventory:

 

Butyl Acetate (123-86-4) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 5000lbs

 

Ethyl Acetate (141-78-6) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 5000lbs

 

Nitrocellulose (9004-70-0) EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e., Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40CFR 710(C)).

 

Isopropyl Alcohol (67-63-0) SARA Section 311/312 Hazard Classes Fire Hazard

 

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Flam. Liq. 2 H225. Acute Tox. 4 (Oral) H302, Skin Irrit. 2 H315, Eye Irrit. 2A H319, STOT SE 3 H336

 

US Regulations

Butyl Acetate (123-86-4)

U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities

U.S. - Washington - Permissible Exposure Limits – TWAs

U.S. - Washington - Permissible Exposure Limits - STELs

U.S. - New Jersey - Right to Know Hazardous Substance List

U.S. - New York - Right to Know List of Hazardous Substances

U.S. - Pennsylvania - List of Hazardous Substances

 

Ethyl Acetate (141-78-6)

U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities

U.S. - New York - Right to Know List of Hazardous Substances

U.S. - New Jersey - Right to Know Hazardous Substance List

U.S. - Pennsylvania - List of Hazardous Substances

U.S. - Washington - Permissible Exposure Limits – TWAs

U.S. - Washington - Permissible Exposure Limits – STELs

 

Nitrocellulose (9004-70-0)

U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities

U.S. - New York - Right to Know List of Hazardous Substances

U.S. - New Jersey - Right to Know Hazardous Substance List

 

Isopropyl Alcohol (67-63-0)

U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations

U.S. - New York - Right to Know List of Hazardous Substances

U.S. - New Jersey - Right to Know Hazardous Substance List

U.S. - Washington - Permissible Exposure Limits - TWAs

U.S. - Washington - Permissible Exposure Limits - STELs

 

 

NFPA                                                                       HMIS

Health            1                                                         Health             1

Fire                3                                                         Fire                 3

Reactivity      0                                                         Reactivity       0     

                                                                                  PPE                G                                           

 

 

  1. 1.       OTHER INFORMATION

 

Disclaimer of Liability:

Glow Inc..  makes no warranty of any kind regarding the information furnished herein. Users should independently determine the suitability and completeness of information from all sources. While this data is presented in good faith and believed to be accurate, it should be considered only as a supplement to other information gathered by the user. It is the User's responsibility to assure the proper use and disposal of these materials as well as the safety and health of all personnel who may work with or otherwise come in contact with these materials

 

Revision 1.GHS 

Date 3/28/2019

 

 

 

 

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